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What volume of water should be added to 600.mL of ethanol in order to have a solution that boils at 95.0°C? (For ethanol, Kb = 1.22 °C/m, density = 0.789 g/cm3, boiling point = 78.4°C)


A) 186 mL
B) 245 mL
C) 518 mL
D) 116 mL
E) 322 mL

F) C) and D)
G) A) and B)

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What is the percent CsCl by mass in a 0.711 M CsCl solution that has a density of 1.091 g/mL?


A) 3.87 * 10-4 %
B) 3.87 * 10-1 %
C) 11.0 %
D) 1.10 %
E) 6.50 * 10-2 %

F) C) and D)
G) D) and E)

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Calculate the percent by mass of potassium nitrate in a solution made from 45.0 g KNO3 and 295 mL of water. The density of water is 0.997 g/mL.


A) 1.51 %
B) 7.57 %
C) 13.3 %
D) 15.2 %
E) None of these

F) A) and D)
G) C) and D)

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Arrange the following aqueous solutions in order of increasing boiling points: 0.050 m Mg(NO3) 2; 0.100 m ethanol; 0.090 m NaCl.


A) Mg(NO3) 2 < NaCl < ethanol
B) ethanol < Mg(NO3) 2 < NaCl
C) ethanol < NaCl < Mg(NO3) 2
D) NaCl < ethanol < Mg(NO3) 2
E) Mg(NO3) 2 < ethanol < NaCl

F) A) and E)
G) A) and B)

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What volume of ethanol (density = 0.7893 g/cm3) should be added to 450.mL of water in order to have a solution that freezes at -15.0°C? (For water, Kf = 1.86 °C/m.)


A) 371 mL
B) 470 mL
C) 212 mL
D) 132 mL
E) 167 mL

F) A) and E)
G) A) and C)

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What is the molarity of a solution that is 7.00% by mass magnesium sulfate and has a density of 1.071 g/mL?


A) 0.0890 M
B) 0.496 M
C) 0.543 M
D) 0.623 M
E) 1.32 M

F) A) and C)
G) None of the above

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For dilute aqueous solutions, the concentration units molarity and molality have almost the same values.

A) True
B) False

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Plasma is the fluid portion of blood.The concentration of acetylsalicylic acid (aspirin, C9H8O4, molar mass = 180.g/mol)in your plasma is found to be 2.99 * 10-4 M after you take two tablets of aspirin.If the volume of your plasma is 5.85 L, how many grams of aspirin are in your blood? (Assume that the density of plasma is 1.00 g/mL.)

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The solubility of CO2 gas in water


A) increases with increasing gas pressure.
B) increases with decreasing gas pressure.
C) decreases with increasing gas pressure.
D) is not dependent on pressure.

E) B) and C)
F) All of the above

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In which of the following solvents would you expect KBr to be most soluble?


A) C6H14 (hexane)
B) CH3CH2OH (ethanol)
C) C6H6 (benzene)
D) CCl4 (carbon tetrachloride)
E) C6H12 (cyclohexane)

F) D) and E)
G) A) and B)

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Dissolving a solute such as KOH in a solvent such as water results in


A) an increase in the melting point of the liquid.
B) a decrease in the boiling point of the liquid.
C) a decrease in the vapor pressure of the liquid.
D) no change in the boiling point of the liquid.

E) None of the above
F) A) and B)

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A 15.00 % by mass solution of lactose (C12H22O11, 342.30 g/mol) in water has a density of 1.0602 g/mL at 20°C.What is the molarity of this solution?


A) 0.03097 M
B) 0.4133 M
C) 0.4646 M
D) 1.590 M
E) 3.097 M

F) All of the above
G) A) and E)

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Calculate the mass of solute in the following solution: 50.0 mL of 0.0300 M C12H22O11.

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What is the molality of a solution that is 3.68 % by mass calcium chloride.


A) 0.0332 m
B) 0.332 m
C) 0.344 m
D) 0.464 m
E) 0.506 m

F) B) and D)
G) B) and C)

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According to Raoult's law, which statement is false?


A) The vapor pressure of a solvent over a solution decreases as its mole fraction increases.
B) The solubility of a gas increases as the temperature decreases.
C) The vapor pressure of a solvent over a solution is less than that of pure solvent.
D) The greater the pressure of a gas over a solution the greater its solubility.
E) Ionic solutes dissociate in solution causing an enhancement of all colligative properties.

F) B) and E)
G) A) and E)

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What is the freezing point of a solution that contains 10.0 g of glucose (C6H12O6) in 100.g of H2O? Kf for water is 1.86°C/m.


A) -0.186°C
B) +0.186°C
C) -0.10°C
D) +0.10°C
E) -1.03°C

F) All of the above
G) A) and B)

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Explain the following, on the basis of osmosis or osmotic pressure: An effective way to kill a snail or slug in your garden is to sprinkle it with salt.

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The water leaves the...

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A 9.50 % by mass solution of acetone (C3H6O) in water has a density of 0.9849 g/mL at 20°C.What is the molarity of this solution?


A) 0.621 M
B) 1.61 M
C) 1.66 M
D) 1.71 M
E) 16.9 M

F) B) and C)
G) All of the above

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Which one of the following would be immiscible with water? Which one of the following would be immiscible with water?

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The density of a 20.3 M CH3OH (methanol) solution is 0.858 g/mL. What is the molality of this solution? H2O is the solvent.


A) 17.4 m
B) 20.8 m
C) 23.7 m
D) 70.0 m
E) 97.6 m

F) C) and E)
G) D) and E)

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